With regard to methane reformingbased hydrogen production processes, a combination of partial oxid ation and steam reforming of methane in an autothermal reform ing atr reactor has recently become more popular. Compact multifuel autothermal reforming catalytic reactor for h2. Proven atr technology for modern largescale methanol plants. Autothermal reforming of natural gas to synthesis gas. Advanced modelling and optimisation of natural gas. Proven autothermal reforming technology for modern largescale methanol plants per juul dahl. Effect of catalytic cylinders on autothermal reforming of. Preliminary modeling and design of an autothermal reformer. Sep 24, 20 steam reforming types of reformer design 1. Using this model, the reactor design is performed and key operational parameters are investigated in order to increase both h 2 yield and h 2 co selectivity. Using this model, the reactor design is performed and key operational parameters are investigated in order to increase both h 2 yield. Haldor topsoe autothermal reformingbased process 17.
It was desired to construct a simulation of a methane autothermal reforming system to identify potential design issues and obtain a preliminary estimate of. Autothermal reforming atr, based on mixing air in with the steamfuel mixture, is an autothermal adaptation of steam reforming. There are multiple types of reformers in development but the most common in industry are autothermal reforming atr and steam methane. Reformer, temperature control, autothermal, methanol, copperzinc oxide catalyst 1. This dissertation presents initial developments on ngr modelling in gproms. Catalytic partial oxidation cpox requires the use of a catalyst, and the. Maarten biesheuvel and gert jan kramer shell global solutions international b. Autothermal reforming atr prototype for pure hydrogen production. These challenges result from the physical and chemical properties of diesel fuel. Kinetics, catalysis and mechanism of methane steam reforming thesis submitted to the faculty of the. Modak department of chemical engineering indian institute of science, bangalore. Integrated autothermal reactor concepts for oxidative coupling and reforming of methane. Standalone autothermal reforming atr is advantageous because it does not require the supply or.
Abstract the conceptual design of compact, standalone autothermal reforming systems using methanol is presented. Autothermal reforming atr is a lowinvestment process using a simple reactor design. Toyo mrfz methanol reactor design 96 toyos methanol synthesis catalyst 98 reaction conditionsparameters 98. Model versus experiment results were compared for three cases. Change of the hotspot point due to the catalyst degradation was investigated and it could be used to design an adaptive controller.
Kinetics, catalysis and mechanism of methane steam reforming. There are multiple types of reformers in development but the most common in industry are autothermal reforming atr and steam methane reforming smr. Prereforming prereforming is the term applied to the low temperature steam reforming of hydrocarbons in a simple adiabatic reactor using highly active, nickel based catalyst, which promotes the steam reforming reaction at low temperatures. The reactor model considers a mass balance equation for each component, and the. The lower operating temperature of catalytic autothermal reforming has several advantages including less complicated reactor design, wider choice of materials for.
The two main reformers, the steam methane reformer smr and the autothermal reformer atr were modelled. The process is sootfree due to burner design and fixedbed catalyst. In this autothermal reactor, an exothermic reaction takes place in a packed bed of catalyst a plug flow tubular reactor. Pdf the autothermal low temperature catalytic partial oxidation of methane was investigated in a bench scale reactor 1 kw th power over a. Design and performance of a kw scale reformer using pure oxygen as oxidant article pdf available january 2006 with 1,787 reads how we measure reads. However, further research is required to optimize the performance of autothermal reformers and accurate models of reactor performance must be developed and validated. Autothermal reforming has been widely used for the production of ammonia and methanol. Mann prepared by sandia national laboratories albuquerque, new mexico 87185 and livermore, california 94550 sandia is a multiprogram laboratory operated by sandia corporation. Autothermal reforming atr is an important industrial process used to produce syngas with a low h2co ratio from 1. Pre reforming pre reforming is the term applied to the low temperature steam reforming of hydrocarbons in a simple adiabatic reactor using highly active, nickel based catalyst, which promotes the steam reforming reaction at low temperatures. Hence, the autothermal reactor is more compact and practical for use in the methanol production process11. Autothermal reforming atr syngas generation catalystbased syngas generation through partial oxidation and subsequent reforming of gaseous feed autothermal reforming atr is a process for producing syngas, composed of hydrogen and carbon monoxide, by partially oxidizing a hydrocarbon feed with oxygen and steam and subsequent catalytic. The autothermal reformer reactor and the secondary reformer are very similar.
Reactor system of a petroleum naphtha catalytic reforming plant. Reforming with steam catalytic natural gas and light hydrocarbons. A novel reactor type for autothermal reforming of diesel fuel. Reforming of diesel fuel for transportation applications. It is considered as the preferred technology for gas to liquid plants. An autothermal reformer for converting a fuel into a reformate stream comprising hydrogen comprises a a closed vessel having a top end and a bottom end, the vessel comprising at least one insulation layer adjacent the interior surface of the vessel. A methane reformer is a device based on steam reforming, autothermal reforming or partial oxidation and is a type of chemical synthesis which can produce pure hydrogen gas from methane using a catalyst. Autothermal reforming an overview sciencedirect topics. Design and control of standalone autothermal reforming. Standalone autothermal reforming atr is advantageous because it does not require the supply or dissipation of thermal energy to or from the reaction. Partial oxidation reactions occur in a region of the reactor referred to as the. Chapter 1 introduction this thesis presents a master of science degree project conducted at the department of chemical engineering, at ntnu.
Microkinetic analysis for model reduction marm dixita, renika baruaha, dhrupad parikha, sudhanshu sharmaa, atul bhargava,1 aenergy systems laboratory, iit gandhinagar, ahmedabad, gujarat, india abstract methane autothermal reforming has been studied using comprehensive, detailed microkinetic. Autothermal cyclic reforming and h2 refueling system. Advanced modelling and optimisation of natural gas reforming. Developed in the late 50s, atrs main application was for ammonia and methanol syntheses. The paper describes the pilot plant concept, its main design features, experiences. Operating data used to identify best design and to tune the design. Steammethane reforming is practiced industrially using several different reactor designs. The process was developed to produce a syngas intermediate from natural gas to synthesize methanol, ammonia, and fischertropsch liquids, due to its production of a syngas with a typical h 2 co ratio of about 2. The gtl plant design has two parallel trains each consisting of a world scale air separation plant, an autothermal reformer, and a slurry phase fischertropsch reactor.
The reactor design of the atr, as well as oxygenblown secondary reformers, consists of a burner, a. Methanol plant process layout with topsoe twostep reforming 14. Twosection reactor model for autothermal reforming of. The model was developed with experimental data from temperature profiles along the reactor and product composition co2, co, and h2 formation. The autothermal reforming technology has been widely discussed in the past on con. A new multicylinder microchamber reactor is designed on autothermal reforming of methane for hydrogen production, and its performance and thermal behavior, that is, based on the reaction mechanism, is numerically investigated by varying the cylinder. The proposed mathematical has been checked successfully against data available in the open literature. This paper will focus on the development of a reactor model that describes the approach to. Production of hydrogen platefin reformer catalyst can be a surface coating or a porous insert. Basic objectives in design of a reactor in chemical engineering physical operations such as fluid flow, heat transfer, mass transfer and separation processes play a very large part.
Determination of optimal process flowrates and reactor design for autothermal hydrogen production in a heatintegrated ceramic microchannel network. The thesis studies the simulation, optimization and control structure design using stepwise approach of skogestad. Based on specific conditions of maximum waste heat recovery, the optimization algorithm for maximizing hydrogen yield is obtained. Thermodynamic analysis of autothermal reforming of synthetic. Autothermal reactor operation if a reaction requires a relatively high temperature before it will proceed at a. Mar 06, 20 describes the operation and the equations used to model an autothermal reactor. Optimization of a methane autothermal reformingbased. Autothermal reforming, or atr, combines steam methane reforming and partial oxidation into a single reactor.
A mathematical model for an autothermal reforming atr fuel processor has been developed to study the transient response of the reactor for gasoline reforming. Nonthermal plasmaassisted partial oxidation of methane. Need to match the heat release rate with the steam hydrocarbon reforming rate. Castaldi earth and environmental engineering hksm, columbia university, 500 west 120th street, new york, 10011 ny. The influence of the main operating variables on the reactor performance is studied. The feed gas enters an annular region around the packed bed, but flows in the opposite direction from that in the packed bed. Autothermal reactor learncheme educational resources for. Because co is denatured to h2 of equivalent mol volume in the poststage shift reactor of an autothermal reformer. In particular, the technical approach used for the design and execution of the demonstration plants and the relevant peculiarities are outlined. Hydrogen production via autothermal reforming atr is particularly attractive for applications that demand a quick startup and response time in a compact size. An original design of atr membrane reactor has been developed.
Production of hydrogen simultaneous separationreaction. Syncor autothermal reformer atr autothermal reforming at low steamtocarbon ratio the majority of the worlds syngasproducing plants apply steam methane reforming, with the specific type of reforming technology depending on application and operating conditions. Autothermal reforming ofjp8 in a catalytic fins reactor federico barrai, marco j. Thermodynamic assessment and autothermal reactor design. Pdf modeling an simulation of an autothermal reformer. On the other hand, the process of combined reforming utilizes both of primary and secondary tools for production of synthesis gas, as it is commonly practiced in ammonia manufacturing. Optimization of a methane autothermal reformingbas ed hydrogen. A new multicylinder microchamber reactor is designed on autothermal reforming of methane for hydrogen production, and its performance and thermal behavior, that is, based on the reaction mechanism, is numerically investigated by varying the cylinder radius, cylinder spacing, and cylinder layout. Autothermal reforming atr syngas generation air liquide.
Autothermal reforming of natural gas to synthesis gas reference. Diesel reforming poses several unique technical challenges, however. Autothermal reformer an overview sciencedirect topics. The various reactor designs, fuel delivery systems and catalysts and. Pdf the steadystate operation of the autothermal reformer is. Cameron, in studies in surface science and catalysis, 2001. Reformer, temperature control, autothermal, methanol, copperzinc.
Autothermal reforming of gasoline for fuel cell applications. Vanden bussche in a fixed bed reactor lurgi technology. A novel reactor concept with autothermal operation is presented for the simultaneous production of ethylene by oxidative coupling ocm and synthesis gas by steam reforming of methane srm. Keywords autothermal reforming, synthesis gas, reactor modeling. This feature makes atr useful for many applications, and it has been proven industrially to provide quality syngas for largescale plants. The structuring of the catalytic functions inside a single catalyst. Determination of optimal process flowrates and reactor. To better understand diesel reforming and the chemistry involved, we have investigated the autothermal reforming of several major diesel constituents in a kilowattscale reactor. However, for reactor design and catalyst development, nonequilibrium reactor modeling is required. We also present and validate a smallscale reactor model for the autothermal reforming of methane atr. In particular, great effort was devoted to the design of the delivery system for liquid hydrocarbons, in order to obtain a quick vaporization, an uniform reactants. A novel reactor type for autothermal reforming of diesel. Autothermal reactor learncheme educational resources.
Autothermal reforming of methane on rhodium catalysts. The modeling, kinetic analysis, and simulation of atr o f methane for prescribed reactors have been studied 1012. Tubular reforming and autothermal reforming of natural gas an. Proven autothermal reforming technology for modern large. Steam methane reforming smr and autothermal reformer atr are two industrial examples of the primary and secondary reformers, respectively.